Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 318151
Title Reductive deamination as a new step in the anaerobic microbial degradation of halogenated anilines
Author(s) Travkin, V.; Baskunov, B.P.; Golovlev, E.L.; Boersma, M.G.; Boeren, S.; Vervoort, J.; Berkel, W.J.H. van; Rietjens, I.M.C.M.; Golovleva, L.A.
Source FEMS Microbiology Letters 209 (2002)2. - ISSN 0378-1097 - p. 307 - 312.
DOI http://dx.doi.org/10.1111/j.1574-6968.2002.tb11149.x
Department(s) Biochemistry
Sub-department of Toxicology
VLAG
WIMEK
Publication type Refereed Article in a scientific journal
Publication year 2002
Abstract In this paper we report the isolation and characterization of an anaerobic enrichment culture as well as of a Rhodococcus sp. strain 2 capable of degrading 3,4-dihaloanilines under nitrate reducing conditions. Using mass spectrometry several of the intermediates formed in the process of 3,4-dichloroaniline conversion were identified. Most interesting is the observation of reductive deamination and the formation of 1,2-dichlorobenzene as one of the intermediates. Using 19F NMR and fluorinated 3,4-dihaloaniline model substrates it was corroborated that reductive deamination of the anilines to give dihalobenzene intermediates represents a new initial step in the anaerobic microbial degradation of these halogenated anilines.
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