Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 346512
Title Effect of Permeability on Aqueous Biopolymer Interfaces in Spinning Drop Experiments
Author(s) Scholten, E.; Sagis, L.M.C.; Linden, E. van der
Source Biomacromolecules 7 (2006)7. - ISSN 1525-7797 - p. 2224 - 2229.
DOI https://doi.org/10.1021/bm060251l
Department(s) Physics and Physical Chemistry of Foods
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2006
Keyword(s) phase-separated gelatin/dextran - shear-flow - tension - mixtures - relaxation - diffusion - emulsions - blends
Abstract In this paper we show that interfaces in aqueous phase-separated biopolymer mixtures are permeable for all components present in the system. In spinning drop experiments, droplets of the low-density phase decreased up to 90% in volume over a time span of days to weeks, when inserted in a matrix of the high-density phase. We propose an expression for this change of volume in time in terms of diffusion coefficients of the components. From the magnitude of these coefficients, we conclude that the transfer of gelatin from inside the droplet to the outer phase was the rate-determining step in this process. Since the interfaces are permeable to all components, the properties of the system change in time. Therefore, the spinning drop technique is not an accurate method for the measurement of the equilibrium interfacial tension of these aqueous phase-separated systems.
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