Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 362291
Title Micellization of telechelic associative polymers: self-consistent field modelling and comparison with scaling concepts
Author(s) Sprakel, J.H.B.; Besseling, N.A.M.; Leermakers, F.A.M.; Cohen Stuart, M.A.
Source The Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical 111 (2007)11. - ISSN 1520-6106 - p. 2903 - 2909.
DOI https://doi.org/10.1021/jp0683768
Department(s) Physical Chemistry and Colloid Science
Publication type Refereed Article in a scientific journal
Publication year 2007
Keyword(s) interacting chain molecules - triblock copolymers - statistical-theory - micelle formation - adsorption - surfaces - surfactants - oxide) - block - size
Abstract We present numerical results from self-consistent field calculations on the micellization of telechelic associative polymers and their mono-functional analogues. These results are confronted with relatively simple scaling concepts. The proportionality of the critical micelle concentration (CMC) with the hydrophilic backbone length, as found in the calculations, shows good correspondence with a scaling argument based on the entropic penalty of loop formation. It is also shown that models for the conformation of spherical brushes can be applied to predict the structure of the flowerlike micelles formed by these telechelic polymers. Furthermore, we find good agreement between the numerical dependence of the aggregation number upon both backbone and terminal hydrophobe length and an analytical expression derived from the well-known Daoud-Cotton model by introducing a correction for the finite size of the micellar core.
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