Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 371499
Title Kinetics of metal ion binding by polysaccharide colloids
Author(s) Rotureau, E.; Leeuwen, H.P. van
Source The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment, & General Theory 112 (2008)31. - ISSN 1089-5639 - p. 7177 - 7184.
DOI https://doi.org/10.1021/jp800472g
Department(s) Physical Chemistry and Colloid Science
WIMEK
Publication type Refereed Article in a scientific journal
Publication year 2008
Keyword(s) deposition potential sscp - stripping chronopotentiometry - speciation dynamics - ligand dispersions - part 1 - complexes - lability - features - voltammetry - dextran
Abstract The dynamics of metal sorption by a gel-like polysaccharide is investigated by means of the electrochemical technique of stripping chronopotentiometry (SCP). The measured response reflects the diffusive flux properties of the metallic species in the dispersion. The colloidal ligand studied here is a functionalized carboxymethyldextran. Its complexation with Pb(II) reveals a time dependence that identifies strong differences in the dynamic nature of the successive metal complexes formed. Apparently, the formation of intramolecular bidentate complexes requires a slow conformational reorganization of the macromolecule that becomes the rate-limiting step in the complexation reaction. The relevant parameters for metal binding and release kinetics are computed and thus provide knowledge of the time-dependent stability and lability of metal polysaccharide complexes.
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