Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 423862
Title Selective Oxidative Decarboxylation of Amino Acids to Produce Industrially Relevant Nitriles by Vanadium Chloroperoxidase
Author(s) But, A.; Notre, J.E.L. le; Scott, E.L.; Wever, R.; Sanders, J.P.M.
Source ChemSusChem 5 (2012)7. - ISSN 1864-5631 - p. 1199 - 1202.
DOI http://dx.doi.org/10.1002/cssc.201200098
Department(s) Biobased Chemistry and Technology
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2012
Keyword(s) fungus curvularia-inaequalis - renewable chemicals - glutamic-acid - biomass - bromoperoxidase - bromination - conversion - enzyme
Abstract Industrial nitriles from biomass: Vanadium-chloroperoxidase is successfully used to transform selectively glutamic acid into 3-cyanopropanoic acid, a key intermediate for the synthesis of bio-succinonitrile and bio-acrylonitrile, by using a catalytic amount of a halide salt. This clean oxidative decarboxylation can be applied to mixtures of amino acids obtained from plant waste streams, leading to easily separable nitriles.
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