Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 431285
Title Natural colloids are the dominant factor in the sedimentation of nanoparticles
Author(s) Quik, J.T.K.; Cohen Stuart, M.A.; Wouterse, M.; Peijnenburg, W.; Hendriks, A.J.; Meent, D. van de
Source Environmental Toxicology and Chemistry 31 (2012)5. - ISSN 0730-7268 - p. 1019 - 1022.
DOI https://doi.org/10.1002/etc.1783
Department(s) Physical Chemistry and Colloid Science
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2012
Keyword(s) engineered nanomaterials - aquatic environments - oxide nanoparticles - humic-acid - aggregation - fate - exposure - challenges - deposition - transport
Abstract Estimating the environmental exposure to manufactured nanomaterials is part of risk assessment. Because nanoparticles aggregate with each other (homoaggregation) and with other particles (heteroaggregation), the main route of the removal of most nanoparticles from water is aggregation, followed by sedimentation. The authors used water samples from two rivers in Europe, the Rhine and the Meuse. To distinguish between small (mainly natural organic matter [NOM]) particles and the remainder of the natural colloids present, both filtered and unfiltered river water was used to prepare the particle suspensions. The results show that the removal of nanoparticles from natural river water follows first-order kinetics toward a residual concentration. This was measured in river water with less than 1¿mg¿L-1 CeO2 nanoparticles. The authors inferred that the heteroaggregation with or deposition onto the solid fraction of natural colloids was the main mechanism causing sedimentation in relation to homoaggregation. In contrast, the NOM fraction in filtered river water stabilized the residual nanoparticles against further sedimentation for up to 12¿d. In 10¿mg¿L-1 and 100¿mg¿L-1 CeO2 nanoparticle suspensions, homoaggregation is likely the main mechanism leading to sedimentation. The proposed model could form the basis for improved exposure assessment for nanomaterials.
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