Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 435914
Title Microscopic Origin of the Fast Blue-Green Luminescence from Chemically Synthesized Non-Oxidized Silicon Quantum Dots
Author(s) Dohnalová, K.; Gregorkiewicz, T.; Fucíková, A.; Valenta, J.; Umesh, C.; Paulusse, J.M.J.; Zuilhof, H.; Humpolícková, J.; Hof, M. van
Source Small 8 (2012)20. - ISSN 1613-6810 - p. 3185 - 3191.
DOI http://dx.doi.org/10.1002/smll.201200477
Department(s) Laboratory for Organic Chemistry
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2012
Keyword(s) light-emission - confinement regime - electronic states - si nanocrystals - porous silicon - photoluminescence - nanoparticles - alkyl - nanoclusters - spectroscopy
Abstract The microscopic origin of the bright nanosecond blue-green photoluminescence (PL), frequently reported for synthesized organically terminated Si quantum dots (Si-QDs), has not been fully resolved, hampering potential applications of this interesting material. Here a comprehensive study of the PL from alkyl-terminated Si-QDs of 2-3 nm size, prepared by wet chemical synthesis is reported. Results obtained on the ensemble and those from the single nano-object level are compared, and they provide conclusive evidence that efficient and tunable emission arises due to radiative recombination of electron-hole pairs confined in the Si-QDs. This understanding paves the way towards applications of chemical synthesis for the development of Si-QDs with tunable sizes and bandgaps.
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