Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 451137
Title Geochemical and Microbiological Characteristics during in Situ Chemical Oxidation and in Situ Bioremediation at a Diesel Contaminated Site
Author(s) Sutton, N.B.; Kalisz, M.; Krupanek, J.; Marek, J.; Grotenhuis, J.T.C.; Smidt, H.; Weert, J. de; Rijnaarts, H.H.M.; Gaans, P. van; Keijzer, T.
Source Environmental Science and Technology 48 (2014)4. - ISSN 0013-936X - p. 2352 - 2360.
DOI http://dx.doi.org/10.1021/es404512a
Department(s) Sub-department of Environmental Technology
Microbiological Laboratory
WIMEK
Publication type Refereed Article in a scientific journal
Publication year 2014
Keyword(s) activated persulfate oxidation - soil organic-matter - fentons reagent - biodegradation - remediation - degradation - oxidants - ozonation - peroxide - minerals
Abstract While in situ chemical oxidation with persulfate has seen wide commercial application, investigations into the impacts on groundwater characteristics, microbial communities and soil structure are limited. To better understand the interactions of persulfate with the subsurface and to determine the compatibility with further bioremediation, a pilot scale treatment at a diesel-contaminated location was performed consisting of two persulfate injection events followed by a single nutrient amendment. Groundwater parameters measured throughout the 225 day experiment showed a significant decrease in pH and an increase in dissolved diesel and organic carbon within the treatment area. Molecular analysis of the microbial community size (16S rRNA gene) and alkane degradation capacity (alkB gene) by qPCR indicated a significant, yet temporary impact; while gene copy numbers initially decreased 1–2 orders of magnitude, they returned to baseline levels within 3 months of the first injection for both targets. Analysis of soil samples with sequential extraction showed irreversible oxidation of metal sulfides, thereby changing subsurface mineralogy and potentially mobilizing Fe, Cu, Pb, and Zn. Together, these results give insight into persulfate application in terms of risks and effective coupling with bioremediation.
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