Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 495818
Title Dynamical heterogeneities and defects in two-dimensional soft colloidal crystals
Author(s) Meer, B. Van Der; Qi, W.; Sprakel, J.; Filion, L.; Dijkstra, M.
Source Soft Matter 11 (2015)48. - ISSN 1744-683X - p. 9385 - 9392.
DOI https://doi.org/10.1039/c5sm01520k
Department(s) Physical Chemistry and Soft Matter
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2015
Abstract

In this paper we study a two-dimensional system of charged colloidal particles using Brownian dynamics simulations. We determine the phase diagram and investigate the dynamics of this system in the density regime where hexatic and solid phases are stable. We find that the dynamics in these phases is heterogeneous by means of the spontaneous formation and diffusion of highly mobile defects. We identify two key mechanisms associated with the areas of high mobility. The first mechanism involves the highly cooperative motion of a closed loop of particles which shift coherently along the loop until each particle has replaced the position of its predecessor in the chain. The second mechanism involves the spontaneous creation of vacancy-interstitial pairs which diffuse within the hexatic and solid phases. We further explore quantitatively the properties of the open-ended and closed rearrangement strings and find that in the crystal phase the string-size distribution can be approximately matched with a simple, random walk description of vacancies and interstitials on a lattice.

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