Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 496739
Title The Weak Interaction of Surfactants with Polymer Brushes and Its Impact on Lubricating Behavior
Author(s) Zhang, Ran; Ma, Shuanhong; Wei, Qiangbing; Ye, Qian; Yu, Bo; Gucht, Jasper Van Der; Zhou, Feng
Source Macromolecules 48 (2015)17. - ISSN 0024-9297 - p. 6186 - 6196.
DOI http://dx.doi.org/10.1021/acs.macromol.5b01267
Department(s) Physical Chemistry and Soft Matter
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2015
Abstract

We study the weak interaction between polymers and oppositely charged surfactants and its effect on the lubricating behavior and wettability of polymer brush-covered surfaces. For cationic (PMETAC) and anionic (PSPMA) brushes, a gradual transition from ultralow friction to ultrahigh friction was observed upon adding oppositely charged surfactant as a result of the electrostatic and hydrophobic interactions between surfactant and polymer. The surfactant exchange led to a strong dehydration of the brush and a concomitant increase in friction. Upon adding surfactant above the CMC, we find a reduction in friction for the anionic brushes, while the cationic brushes maintain a high friction. This difference between the two lubrication systems suggests a different interaction mechanism between the polymers and the surfactants. For zwitterionic (PSBMA) and neutral (POEGMA) polymer brushes, where electrostatic and hydrophobic interactions could be negligible, there is nearly no surfactant uptake and also no effect of surfactant on lubrication.

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