Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 505862
Title Yielding and flow of cellulose microfibril dispersions in the presence of a charged polymer
Author(s) Kort, Daan W. De; Veen, Sandra J.; As, Henk Van; Bonn, Daniel; Velikov, Krassimir P.; Duynhoven, John P.M. Van
Source Soft Matter 12 (2016)21. - ISSN 1744-683X - p. 4739 - 4744.
DOI http://dx.doi.org/10.1039/c5sm02869h
Department(s) Biophysics
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2016
Abstract

The shear flow of microfibrillated cellulose dispersions is still not wholly understood as a consequence of their multi-length-scale heterogeneity. We added carboxymethyl cellulose, a charged polymer, that makes cellulose microfibril dispersions more homogeneous at the submicron and macro scales. We then compared the yielding and flow behavior of these dispersions to that of typical thixotropic yield-stress fluids. Despite the apparent homogeneity of the dispersions, their flow velocity profiles in cone-plate geometry, as measured by rheo-MRI velocimetry, differ strongly from those observed for typical thixotropic model systems: the viscosity across the gap is not uniform, despite a flat stress field across the gap. We describe these velocity profiles with a nonlocal model, and attribute the non-locality to persistent micron-scale structural heterogeneity.

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