Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 507741
Title Lability of nanoparticulate metal complexes in electrochemical speciation analysis
Author(s) Leeuwen, Herman P. van; Town, Raewyn M.
Source Journal of Solid State Electrochemistry 20 (2016)12. - ISSN 1432-8488 - p. 3255 - 3262.
DOI https://doi.org/10.1007/s10008-016-3372-7
Department(s) Physical Chemistry and Soft Matter
Publication type Refereed Article in a scientific journal
Publication year 2016
Keyword(s) Chemodynamics - Intraparticulate reaction layer - Ion exchange - Lability - Metal complexes
Abstract

Lability concepts are elaborated for metal complexes with soft (3D) and hard (2D) aqueous nanoparticles. In the presence of a non-equilibrium sensor, e.g. a voltammetric electrode, the notion of lability for nanoparticulate metal complexes, M-NP, reflects the ability of the M-NP to maintain equilibrium with the reduced concentration of the electroactive free M2+ in its diffusion layer. Since the metal ion binding sites are confined to the NP body, the conventional reaction layer in the form of a layer adjacent to the electrode surface is immaterial. Instead an intraparticulate reaction zone may develop at the particle/medium interface. Thus the chemodynamic features of M-NP complexes should be fundamentally different from those of molecular systems in which the reaction layer is a property of the homogeneous solution (μ = (DM/ka )1/2). For molecular complexes, the characteristic timescale of the electrochemical technique is crucial in the lability towards the electrode surface. In contrast, for nanoparticulate complexes it is the dynamics of the exchange of the electroactive metal ion with the surrounding medium that governs the effective lability towards the electrode surface.

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