Staff Publications

Staff Publications

  • external user (warningwarning)
  • Log in as
  • language uk
  • About

    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

    We have a manual that explains all the features 

Record number 511128
Title Self-assembly of PS-b-PNIPAM-b-PS block copolymer thin films via selective solvent annealing
Author(s) Cetintas, Merve; Kamperman, Marleen
Source Polymer 107 (2016). - ISSN 0032-3861 - p. 387 - 397.
DOI https://doi.org/10.1016/j.polymer.2016.08.033
Department(s) Physical Chemistry and Soft Matter
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2016
Keyword(s) Block copolymer self-assembly - Hexagonally ordered perpendicular cylinders - PS-b-PNIPAM-b-PS block copolymer - Selective solvent annealing
Abstract Block copolymer (BCP) thin films are interesting material systems for nanofabrication since they can form well-defined periodic nanostructures by microphase separation. However, attaining a specific morphology with the required orientation can be challenging. In this study, we investigated the morphological behavior of polystyrene-b-poly(N-isopropylacrylamide)-b-polystyrene (PS-b-PNIPAM-b-PS) BCP thin films by using Atomic Force Microscopy (AFM) and in-situ Grazing-Incidence X-ray Scattering (GISAXS) during selective solvent annealing. Thin films of a lamellar BCP were annealed by using various solvents with different selectivity for the blocks, such as PNIPAM-selective methanol, non-selective tetrahydrofuran (THF) and PS-selective toluene. Solvent annealing using methanol: THF 1:2 (v:v) or methanol: toluene 1:1 (v:v) resulted in the formation of hexagonally ordered perpendicular cylinders, whereas no sustained long-range order was found when only one type of solvent was used. PS-b-PNIPAM-b-PS BCP thin films that have hexagonally ordered perpendicular cylinders are promising for applications where thermo-responsiveness is desired, such as nanofiltration and biomedical applications.
Comments
There are no comments yet. You can post the first one!
Post a comment
 
Please log in to use this service. Login as Wageningen University & Research user or guest user in upper right hand corner of this page.