Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 534691
Title Continuous electrochemical oxidation of biomass derived 5-(hydroxymethyl)furfural into 2,5-furandicarboxylic acid
Author(s) Latsuzbaia, R.; Bisselink, R.; Anastasopol, A.; Meer, H. van der; Heck, R. van; Yagüe, M.S.; Zijlstra, M.; Roelands, M.; Crockatt, M.; Goetheer, E.; Giling, E.
Source Journal of Applied Electrochemistry 48 (2018)6. - ISSN 0021-891X - p. 611 - 626.
DOI https://doi.org/10.1007/s10800-018-1157-7
Department(s) FBR Sustainable Chemistry & Technology
Publication type Refereed Article in a scientific journal
Publication year 2018
Keyword(s) Continuous production - Electroorganic synthesis - FDCA - HMF - Nickel oxy-hydroxide electrode
Abstract Abstract: A continuous electrochemical process with integrated product separation has been developed for production of 2,5-furandicarboxylic acid (FDCA) by oxidation of 5-(hydroxymethyl)furfural (HMF) in aqueous alkaline media on non-noble Ni/NiOOH foam electrodes at ambient conditions. Initially, voltammetry studies were performed in both, acid and alkaline media, on various catalyst materials: Au, Au3Pd2, Pt, PbO2, Ni/NiOOH and graphite. Preparative electrolysis was performed on Au, Au3Pd2, Pt, PbO2, Ni/NiOOH electrodes in a divided glass cell and Ni/NiOOH showed the best performance with an FDCA yield of ≈ 90% and a Faradaic efficiency of ≈ 80%. The electrolysis conditions were then optimized to industrially relevant conditions in a filter-press type flow reactor with Ni/NiOOH foam anode. HMF concentrations as high as 10 wt% were converted to FDCA at pH 12 in a buffer free 0.1 M Na2SO4 electrolyte with continuous addition of NaOH to maintain constant pH. An FDCA separation yield up to 95% was achieved via pH shift crystallization. The electrolysis and FDCA separation results were used for the design and construction of a bench-scale system where continuous FDCA production, including integrated product separation, was tested and reported in this work. This publication for the first time presents a continuous electrochemical FDCA production system with integrated product separation at industrially relevant product concentrations, 10 wt% HMF, and utilizing non-noble electrode materials. Graphical Abstract: [Figure not available: see fulltext.]
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