Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 536774
Title Strain-Promoted Cycloaddition of Cyclopropenes with o-Quinones : A Rapid Click Reaction
Author(s) Gahtory, Digvijay; Sen, Rickdeb; Kuzmyn, Andriy R.; Escorihuela, Jorge; Zuilhof, Han
Source Angewandte Chemie-International Edition (2018). - ISSN 1433-7851
DOI http://dx.doi.org/10.1002/anie.201800937
Department(s) Laboratory for Organic Chemistry
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2018
Keyword(s) Kinetics - Mass spectrometry - Metal-free click reactions - Monolayers - Polymer brushes
Abstract Novel click reactions are of continued interest in fields as diverse as bio-conjugation, polymer science and surface chemistry. Qualification as a proper "click" reaction requires stringent criteria, including fast kinetics and high conversion, to be met. Herein, we report a novel strain-promoted cycloaddition between cyclopropenes and o-quinones in solution and on a surface. We demonstrate the "click character" of the reaction in solution and on surfaces for both monolayer and polymer brush functionalization.
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