Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

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Photonic Paints: Structural Pigments Combined with Water-Based Polymeric Film-Formers for Structurally Colored Coatings
Clough, Jess M. ; Guimard, Elise ; Rivet, Cindy ; Sprakel, Joris ; Kodger, Thomas E. - \ 2019
Advanced Optical Materials (2019).
colloidal assembly - paints - photonic pigments - structural colors

Paints contain at least two components: a colorant and a polymeric binder, dispersed in a fluid medium. The first imparts color to the paint coating, while the second encapsulates the colorant upon drying in a robust polymeric film adherent to the surface substrate. Photonic pigments, inspired by nature's coloration strategy, hold promise as a replacement for toxic and fade-prone absorptive colorants, most prominently in the fabrication of stable and sustainable water-based paints. Crucially however, the step to combine photonic pigments with polymeric binders has not yet been taken. Here, a water-based paint is designed and realized containing both photonic pigments synthesized by a scalable emulsion process and commercial polymeric binders in an aqueous dispersion. The photonic pigments are silica spheres containing a close-packed array of air pores, of which both the periodicity and degree of long-range ordering can be controlled to produce pigments of varying colors and degrees of iridescence. The readiness of the photonic paints for application is demonstrated by applying them like traditional paints in homages of famous artistic paintings. These findings should stimulate widespread application of structural pigments as colorants in not only paints but also a variety of industrially important materials, such as plastics, inks, or cosmetics.

Christiaan Bolck (Biobased Performance Materials): ‘We doen onderzoek dat impact heeft’
Bolck, Christiaan - \ 2018
biobased economy - biobased materials - biomass - polymers - bioplastics - dyes - pigments - paints - plant extracts
'Veelbelovend en bijna marktrijp' : onderzoek door Wageningen Universiteit Research naar biobased bindmiddelen in verf
Haveren, Jacco van - \ 2017
residual streams - biobased economy - chemicals - biobased chemicals - research - biobased chemistry - binding agents - biopolymers - paints
‘Algen en verf: nog lange weg te gaan' : Wageningse onderzoekers over hogere algenbra
Blaauw, Rolf ; Mooibroek, Hans - \ 2012
paints - algae - algae culture - plant oils - biobased economy - biobased chemistry
Oxidation and oligomerization of ethyl linoleate under the influence of the combination of ascorbic acid 6-palmitate/iron-2-ethylhexanoate
Micciche, F. ; Haveren, J. van; Oostveen, E.A. ; Ming, W. ; Linde, R. van der - \ 2006
Applied Catalysis A-General 297 (2006)2. - ISSN 0926-860X - p. 174 - 181.
unsaturated fatty-acids - metal-catalyzed autoxidation - lipid-peroxidation - mass-spectrometry - alkyd resins - linseed oil - cross-linking - paints - drier - iron(iii)
In this paper we report the oxidation and oligomerization of ethyl linoleate (EL), a model compound for alkyd resins, under the influence of iron-2-ethylhexanoate (Fe-eh) in combination with ascorbic acid 6-palmitate (AsA6p) at different AsA6p/Fe-eh molar ratios (0/1¿4/1). Reactions were studied in time by FT-IR, NMR, size exclusion chromatography (SEC) and peroxide amount determination. The oxidation and oligomerization of EL were accelerated by the combination of AsA6p and Fe-eh, and the catalytic properties of the catalysts were strongly dependent on the molar ratio AsA6p/Fe-eh. The molar ratio of 2/1 appeared to be optimal, at which both the oxidation and oligomerization of EL were the fastest. At molar ratio smaller than 2/1, or only in the presence of Fe-eh, the EL oxidation showed a time lag of up to 100 h; above the ratio 2/1 the rates of both EL oxidation and oligomerization decreased. Results are explained in terms of the multi-facet role played by AsA6p: its pro-oxidant or anti-oxidant properties, depending on the ratio of AsA6p/Fe-eh, and its effect on the Fe-eh complex.
A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings
Oyman, Z.O. ; Ming, W. ; Micciche, F. ; Oostveen, E. ; Haveren, J. van; Linde, R. van der - \ 2004
Polymer 45 (2004)22.. - ISSN 0032-3861 - p. 7431 - 7436.
resins - model - carcinogenicity - autoxidation - mechanisms - oxidation - complex - paints - drier
A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL. (C) 2004 Elsevier Ltd. All rights reserved.
Markten voor groene opties, ervaringen in verpakkingen, verven en isolatiematerialen
Vellema, S. - \ 2003
Wageningen : Agrotechnology & Food Innovations (Groene grondstoffen 3) - ISBN 9067547727 - 42
vervangbare hulpbronnen - industriële gewassen - industriële toepassingen - marketing - biodegradatie - verpakkingsmaterialen - verfsoorten - isolatiematerialen - biobased economy - renewable resources - industrial crops - industrial applications - biodegradation - packaging materials - paints - insulating materials
Het voor u liggende boek is onderdeel van de strategische heroriëntatie betreffende Hernieuwbare Grondstoffen geïnitieerd door het ministerie van Landbouw, Natuur en Voedselkwaliteit (LNV). Het beleid richt zich op de korte termijn (0-5 jaar) en de lange termijn (5-10 jaar). Het korte termijn perspectief relateert innovatie en technologieontwikkeling aan de realiteit in industriële- en consumentenmarkten. In de studie ‘Groene Opties’ hebben Agrotechnology & Food Innovations (A&F, Wageningen University and Research Centre) en BECO Milieumanagement & Advies perspectiefrijke en maatschappelijk relevante product-markt-combinaties onderzocht en geselecteerd. De opdrachtgever LNV wilde meer weten over de oorzaken van de geringe aanwezigheid van ‘Groene Opties’ in de markt en de rol van de overheid in de stimulering van perspectiefrijke alternatieven op basis van hernieuwbare grondstoffen.
Cactus pear and cochineal in Cochabamba: the development of a cross-epistemological management toolkit for interactive design of farm innovation
Tekelenburg, A. - \ 2002
Wageningen University. Promotor(en): N.G. Röling; E.A. Goewie. - S.l. : S.n. - ISBN 9789058084798 - 191
bedrijfssystemen - innovaties - ontwerp - leren - interacties - cactaceae - opuntia ficus-indica - kleur - kleurstoffen (dyes) - verfsoorten - pigmenten - bolivia - coccidae - insecten - plantenplagen - voorlichting - participatie - boeren - integratie - plattelandsontwikkeling - bedrijfsvoering - landbouw - natuurlijke hulpbronnen - nuttig gebruik - bodemdegradatie - wetenschap - farming systems - innovations - design - learning - rural development - management - extension - participation - farmers - agriculture - natural resources - utilization - soil degradation - interactions - integration - insects - plant pests - colour - dyes - paints - pigments - science
<p>In this book, the local research and development process of the small-farmers (campesino) union of Huancarani (Cochabamba region in Bolivia) is discussed. Research activities were carried out by farmers themselves as well as by facilitators and scientists, but the farmers union kept control on planning, evaluation, decision-making and action. The book refers on the one hand to a technical issue; the development of cactus pear (Opuntia ficus-indica M.) and cochineal (Dactylopius coccus C.) production. The main question became why the experience was so successful. On the other hand it refers to a social issue (when the relation between farmers and scientists is addressed and applied methodology is analysed). The intellectual challenge for me was to show to a large and diversified public that, from a particular project, lessons can be drawn to improve interactive learning for farm innovation. This challenge has everything to do with the cooperation and communication issue between farmers and scientists. The exercise covers a reconstructed logic of applied research, design and development methodology and is therefore abstract. The final result of this exercise was the production of the management toolkit for the design of interactive learning processes. This toolkit became a practical instrument for managing and facilitating farm innovation processes in other contexts. It is the <em>development</em> of this toolkit, the learning process, based on the mantra learning in practice - learning from practice - learning for practice, that I want to share with other scientists and development workers.</p>
De veelzijdige aardappel
Oosterhaven, J. ; Schijndel, R. van; Soest, J. van; Tuil, R. van - \ 2000
Aardappelwereld 54 (2000)8. - ISSN 0169-653X - p. 21 - 23.
aardappelen - solanum tuberosum - industriële gewassen - kunststoffen - verwerking - technologie - schuim - verfsoorten - afdeklagen - potatoes - industrial crops - plastics - foams - paints - coatings - processing - technology
Perspectieven voor agrificatie van de aardappel. Van de aardappel worden al gemaakt: lijmen, schuimen, coatings, bindmiddel of verdikkingsmiddel in watergedragen verf en bio-afbreekbare luiers
Alternating side-chain liquid-crystalline copolymers with polar moieties in the backbone = Alternerende zijketen vloeibaar-kristallijne copolymeren met polaire groepen in de hoofdketen
Nieuwhof, R.P. - \ 1999
Agricultural University. Promotor(en): E.J.R. Sudhölter; Ton Marcelis. - S.l. : S.n. - ISBN 9789058081001 - 160
technologie - paint - afdeklagen - onderzoek - corrosie - verfsoorten - vloeibare kristallen - technology - coatings - research - corrosion - paints - liquid crystals
<p>Side-chain liquid-crystalline polymers (SCLCPs) obtained via the alternating copolymeri-zation of maleic anhydride (MA) and mesogenic 1-alkenes are an interesting class of polymers that may show good adhesion towards metal surfaces and form ordered layered structures. If these polymers contain methoxybiphenyl mesogens, they have high glass transition temperatures and exhibit highly ordered mesophases. The mesogen density of these polymers has been increased by coupling mesogen-containing alcohols onto SCLCPs with MA moieties. Depending on the structure of the mesogens of the SCLCP and the alcohols, mesophases were obtained with different degrees of interdigitation of side chains and different degrees of order. Copolymerization of MA with swallow-tailed 1-alkenes having two mesogens yielded polymers with even a higher degree of order. These polymers exhibit isotropization temperatures that were lower and glass transitions that were higher than those of polymers with half the mesogen density. The amount of MA in SCLCPs was altered by copolymerization of MA with mesogenic methacrylates. For methoxybiphenyl mesogens, the isotropization temperature increases with MA content. The temperature window of the mesophase increases with increasing spacer length.<p>A completely new class of SCLCPs was obtained by the copolymerization of carbon monoxide and mesogenic 1-alkenes. For methoxybiphenyl mesogens, these copolymers exhibit highly ordered smectic E mesophases and high glass transition temperatures. The transition temperatures were tuned by altering the spacer length or by dilution of the mesogen content of the copolymer.</p><p>Rheology showed that the loss and storage moduli and the complex viscosity strongly decrease at phase transitions. In addition, a decrease in these properties was observed in the smectic A mesophase which can probably be ascribed to rotational diffusion of the mesogens.</p><p>The Langmuir-Blodgett technique showed that SCLCPs with cyano groups form multilayers on the water subphase. Transfer of SCLCPs with methoxybiphenyl mesogens results in multilayer films with a double layer periodicity, which is different from that observed in the bulk. Annealing of these films results in a more uniform d spacing.</p><p><strong>Dr.ir. R.P. Nieuwhof<br/><strong>TNO Institute of Industrial Technology<br/><strong>Materials Technology Division<br/></p><p><strong>De Wielen 6 Tel.: +31 (0)40 265 0341<br/><strong>P.O. Box 6235 Fax: +31 (0)40 265 0302<br/><strong>5600 HE Eindhoven E-mail: r.nieuwhof@ind.tno.nl<br/><strong>The Netherlands WWW-adres: http://www.tno.nl<br/></p>
Interactions between wood and coatings with low organic solvent content
Meijer, M. de - \ 1999
Agricultural University. Promotor(en): H. Militz; R. van der Linde. - S.l. : S.n. - ISBN 9789058081346 - 177
houtverduurzaming - afdeklagen - verfsoorten - bescherming - oplosmiddelen - oppervlakte-interacties - wood preservation - coatings - paints - protection - solvents - surface interactions
<p>The aim of the work described in this thesis is to improve the knowledge on the fundamental interactions between low VOC-coatings and wood, in particular in relation to wood protection in exterior use. To avoid environmental damage and dangerous conditions in the workplace, low-VOC paints have gained increasing importance by the use of waterborne and so called high solids paints. These low-VOC coatings are more and more being used on wood species with: a reduced natural durability against biological decay, higher fluctuations in wood moisture content and reduced dimensional stability. To maintain a good competitive position for wood in the joinery market a longer product lifetime and lower maintenance demands are needed. This will also contribute to a reduction of the total environmental impact during the life cycle of finished wood. Knowledge on the interactions between wood and low-VOC coatings might contribute to the development of technologies that will enlarge the lifetime and protective capacities of wood coatings.</p><p>This research has focused on understanding three main aspects of the interaction between coatings and wood. The first one deals with the penetration and wetting of low-VOC coatings, in particular waterborne, coatings. The second aspect deals with the adhesion mechanism of a coating on wood. The third part of the research looks into the sorption of moisture and the related dimensional changes of coated wood. In this respect, special attention has been given to the processes occurring at the surface. The research described in <em>chapter 2</em> to <em>7</em> was carried with model paint systems, based on commercially available raw materials. Both pigmented and unpigmented coatings based on acrylic dispersions, acrylic emulsions, alkyd emulsions, solventborne or high solid alkyd resins were used. The research in <em>chapter 8</em> and <em>9</em> was done with commercially available waterborne and solventborne paints. The majority of the work was done on the wood species: spruce <em>(Picea abies)</em> , pine sapwood <em>(Pinus sylvestris)</em> and meranti <em>(Shorea spp.).</p><p>Chapter 1</em> gives an introduction to this thesis and an overview of the background, the protective capacities and the performance of wood coatings.</p><em><p>Chapter 2</em> describes the microscopic investigations of the penetration of coatings in wood. The degree of penetration is determined by the possibility of the flow of a coating into the wood capillaries. This depends both on the structure of the wood and the properties of the coating. For softwoods, three potential penetration routes exist: flow in the axial direction from open ends of capillaries, flow into rays ending at the surface and flow from rays through cross-field pits into adjacent axial tracheids. The permeability of the wood only has an influence on the degree of penetration if the penetration depth exceeds the maximum length of a single cell element. In the case of meranti the penetration is limited to the vessels and rays.</p><p>In <em>chapter 3</em> two quantitative techniques for the measurement of penetration are given. The first one measures the maximum depth of penetration into axial direction on a microscopic scale. The second one determines the penetration rate from the volumetric uptake from the axial surface. The maximum penetration depth can be partially related to the diameter of the axial tracheids but both negative and positive correlations exist. Large differences in the maximum penetration depth between coatings were observed. Generally, acrylic dispersion showed the lowest penetration followed by alkyd emulsions, solventborne and high solid alkyd resins. Addition of pigment has a negative influence on the penetration. The viscosity proved to be an important factor to explain differences between coatings. An increasing wood moisture content (2 to 28 %) caused a deeper penetration.</p><p>The dynamics of capillary flow into wood are further studied in <em>chapter 4</em> using the Washburn-model. Accordingly, the penetration rate is proportional to the capillary radius, the liquid surface tension times the cosine of the contact angle and inversely proportional to the viscosity and the height of capillary rise. During the capillary uptake, water or solvent is selectively taken up into the wood. This causes an increasing solid matter content and hence also increasing viscosity and a decreasing capillary pressure. The waterborne coatings showed a very rapid increase of viscosity with increasing mass fraction of binder. At a mass fraction of about 0.45 to 0.55 the viscosity reaches extremely high values, in particular at low shear rates (&lt; 1 s <sup>-1</SUP>). With solventborne binders this increase is less pronounced. The rapid increase of the viscosity limits the capillary penetration in most cases. The increase in mass fraction of the binder during capillary uptake was calculated from the analysis of evaporation rates on glass and wood. These showed that at least half of the water or solvent was taken up into the wood on first instance. The addition of a thickener decreased the total capillary uptake and enhanced the selective uptake of water. The Washburn-equation can predict the penetration process fairly well in qualitative terms. To obtain quantitative predictions, a correction for the increase in viscosity is needed because in reality the viscosity increase happens faster than is predicted by the model calculations. Additional research showed that capillary uptake was reduced with decreasing surface tension as long as the wetting is complete, this is in agreement with the Washburn equation.</p><p>The surface free energy of wood was determined from the acid-base and Lifshitz-van der Waals components based on contact angle measurements with water, diiodomethane and formamide as described in <em>chapter 5</em> . Different measuring techniques for the contact angle were compared. The obtained angle was shown to be highly dependent on the way the measurement was performed. This is due to the adsorption of liquids onto the wood, the surface roughness and the chemical heterogeneity of the wood. The surface free energy of wood ranged between 40 and 50 mJ m <sup>-2</SUP>with a dominant Lifshitz-van der Waals component. The acid and base parameters were strongly dependent on the measuring conditions.</p><p><em>Chapter 6</em> describes a newly developed method to measure the adhesion quantitatively. The method is based on measuring the force need to peel the coating from the wood by means of a pressure sensitive tape. This method has the advantage of showing differences in adhesion between early- and latewood zones, corresponding to differences in penetration. A disadvantage is the limited maximum measurable force which restricts its application to measurement under wet conditions (wood moisture content over 25 %) where adhesion is lower. The lower adhesion at higher moisture content can partly be explained by the internal stress due the higher expansion of some coatings in comparison to wood. The interfacial of work of adhesion as it was calculated from the surface free energy of coating and wood was positive under both dry and wet conditions.</p><p>The influence of the penetrated coating on the moisture sorption and dimensional change of pine sapwood is described in <em>chapter 7</em> . If compared to a coating present as a film on the surface, the penetrated coating had a very limited influence on the equilibrium moisture content, the water vapour diffusion rate and the dimensional changes. Only the capillary uptake of water was reduced depending on the type of coating. The small influence of the penetrated coating upon the wood moisture content, can partly be explained by the swelling of the coating itself and the relative low void filling due to shrinkage of the coating after drying.</p><p>How a coating can influence the moisture distribution in spruce is given in <em>chapter 8</em> . During long term measurements of the uptake of water, the moisture distribution was determined experimentally and compared with calculated profiles from the apparent diffusioncoefficient. The most realistic prediction was found if the apparent diffusioncoefficient of unfinished wood was used, taking the impact of a coating into account by a reduced moisture content at the surface. Moisture diffuison is the dominant transport mechanism; it is only close to the surface that capillary water uptake is noticeable, in particular with unfinished wood.</p><p><em>Chapter 9</em> studies the adsorption and desorption of water and the dimensional change in spruce and meranti as a function of coating type, film thickness, temperature and relative humidity of the environment. The apparent moisture diffusion coefficients are dependent on all these factors and also on the initial and final wood moisture content. The dimensional change can be described as a function of time by a two-parameter regression model. The rate constant in this model is directly related to the apparent diffusion coefficient, as long as the influence of capillary water uptake is small.</p><p>The general conclusions of this research are given in <em>chapter 10</em> . A certain amount of coating penetration into the wood improves adhesion and prevents rapid capillary water uptake. It was shown that coatings, like wood, can adsorb water and swell. Therefore it is recommended to consider the moisture-related aspects of wood coatings in terms of the differences between both materials. To achieve a good wet adhesion, the dimensional change of the coating and the wood should be in the same range. The surface free energy and the work of adhesion between a coating and wood can not explain the observed differences in adhesion between different coatings. The penetration is mainly controlled by the viscosity of the coating as a function of the solid matter content and the shear rate. In this respect the influence of the carrier medium (water or organic solvent) is more important than the chemical composition of the binder. A positive capillary pressure is, however, a necessity to enable the penetration of a coating into wood. If a coating is present as a film on the surface, the moisture sorption and dimensional change of wood is strongly reduced. The strongest fluctuations in wood moisture content take place directly under the surface. Both waterborne and solventborne coatings largely prevent the rapid capillary uptake of moisture. The moisture uptake into coated wood is a lot slower than in unfinished wood. Therefore in practice a permanent reduction of wood moisture content for both water- and solventborne can be expected.</p><p><strong>Further information can be obtained from:<br/>SHR Timber Research<br/>Mari de Meijer<br/>P.O.Box 497 NL 6700 AL Wageningen<br/>The Netherlands<br/>m.demeijer@shr.nl</strong></p>
Afwerking van vloeren en wanden in stallen met epoxy
Hangelbroek, P.B. - \ 1972
Wageningen : [s.n.] (Mededeling / Instituut voor landbouwbedrijfsgebouwen no. 53) - 3
huisvesting, dieren - verfsoorten - afdeklagen - vernissen - afwerkmiddelen - dierenwelzijn - kleur - industrie - pigmenten - fabricage - kleurstoffen (dyes) - animal housing - paints - coatings - varnishes - finishes - animal welfare - colour - industry - pigments - manufacture - dyes
Beproeving van enkele nieuwe silolakken
Schukking, S. - \ 1962
Wageningen : [s.n.] (Intern rapport / Instituut voor bewaring en verwerking van landbouwprodukten no. 172) - 3
afdeklagen - afwerkmiddelen - verfsoorten - kuilvoerbereiding - silo's - vernissen - coatings - finishes - paints - silage making - silos - varnishes
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