Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 345235
Title Determination of tris(4-chlorophenyl) methanol and tris(4-chlorophenyl) methane in fish, marine mammals and sediment
Author(s) Boer, J. de; Wester, P.G.; Evers, E.H.G.; Brinkman, U.A.Th.
Source Environmental Pollution 93 (1996)1. - ISSN 0269-7491 - p. 39 - 47.
DOI https://doi.org/10.1016/0269-7491(96)00017-6
Department(s) RIVO Milieu en Voedselveiligheid
Publication type Refereed Article in a scientific journal
Publication year 1996
Keyword(s) triphenylmethane dyes - chlorobiphenyls - sea - azo
Abstract Tris(4-chlorophenyl)methanol (TCP) and tris(4-chlorophenyl)methane (TCPMe) were determined in aquatic organisms and sediment by a method based on Soxhlet extraction, gel permeation chromatography, fractionation over silica and gas chromatography/mass spectrometry (GC/MS) analysis. TCPMe was identified as the 4-substituted isomer after synthesis of this compound. TCP could be determined by GC/MS with negative chemical ionistation (GC/NCI-MS) with a detection limit of 0.02 g kg¿1 and a recovery of 90%. TCP concentrations in marine mammals from the North Sea and Dutch Wadden Sea ranged from 0.2 to 2 mg kg¿1, and those in marine and freshwater fish samples from 0.005 to 0.4 mg kg¿1 on a lipid wt basis. TCP concentrations in two Rhine delta sediment samples were 1.2 and 3.0 ¿g kg¿1 dry wt, respectively. TCPMe concentrations, determined by GC/MS with electron impact (GC/EI-MS), were 10¿50% of the TCP concentration in all samples analysed
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