Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 353468
Title Stabilization of Polymersome Vesicles by an Interpenetrating Polymer Network
Author(s) Li, F.; Ketelaar, M.J.; Marcelis, A.T.M.; Leermakers, F.A.M.; Cohen Stuart, M.A.; Sudhölter, E.J.R.
Source Macromolecules 40 (2007)2. - ISSN 0024-9297 - p. 329 - 333.
DOI https://doi.org/10.1021/ma0616763
Department(s) Organic Chemistry
Laboratory of Cell Biology
Physical Chemistry and Colloid Science
VLAG
Publication type Refereed Article in a scientific journal
Publication year 2007
Keyword(s) dilute aqueous-solution - diblock copolymers - triblock copolymer - block-copolymers - force microscopy - drug-delivery - nile red - micelles - microspheres - membranes
Abstract Vesicles from Pluronic L121 (PEO5-PPO68-PEO5) triblock copolymers were stabilized by an interpenetrating polymer network from pentaerythritol tetraacrylate by UV or thermal initiator induced radical polymerization. Fluorescence labeling, atomic force microscopy, and electron microscopy studies were used to study the morphology of the particles and showed that stable vesicles are formed. The block copolymers are noncovalently trapped in the interpenetrating polyacrylate network. The stabilized vesicles retain their size for more than 1 month at room temperature. Upon cooling, the vesicles reversibly lose block copolymer
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