Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 457290
Title Partitioning of humic acids between aqueous solution and hydrogel: Concentration profiling of humic acids in hydrogel phases.
Author(s) Zielinska, K.; Town, R.M.; Yasadi, K.; Leeuwen, H.P. van
Source Langmuir 30 (2014)8. - ISSN 0743-7463 - p. 2084 - 2092.
DOI https://doi.org/10.1021/la4050094
Department(s) Physical Chemistry and Colloid Science
WIMEK
Publication type Refereed Article in a scientific journal
Publication year 2014
Keyword(s) natural organic-matter - fluorescence correlation spectroscopy - diffusion-coefficients - mineral particles - ionic-strength - alginate gel - fulvic-acid - substances - adsorption - soil
Abstract The partitioning of the natural polyelectrolyte humic acid (HA) from an aqueous dispersion into a model biomimetic gel (alginate) and a synthetic polyacrylamide gel (PAAm) is explored. In both gels, the spatial distribution of HA in the gel body, as measured by confocal laser scanning microscopy, is markedly nonhomogeneous. A striking feature is the enhanced accumulation of HA in a thin film of thickness ca. 15 µm at the surface of the gel body, resulting in average local concentrations that are, for PAAm and alginate respectively, a factor of 10 and 4 greater than that in the bulk solution. The time dependence of accumulation in the surface film is predominantly controlled by the diffusive supply of HA from the aqueous medium, with a time constant on the order of 103 s for both gels. The concentration of HA within the bulk gel body differs significantly from that in the bulk aqueous medium: substantially higher for PAAm but much lower for alginate. The results are significant for understanding the nature and rate of sink/source functioning at permeable phases in contact with aqueous media, e.g., biofilms and gel-like layers at biological interfaces or employed in chemical speciation sensors.
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