Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 536556
Title Mesoscale organization of nanoparticle assemblies: looking into superstructures and aggregates
Author(s) Hove, Jan Bart ten
Source Wageningen University. Promotor(en): A.H. Velders, co-promotor(en): F.W.B. van Leeuwen. - Wageningen : Wageningen University - ISBN 9789463438391 - 181
Department(s) BioNanoTechnology
VLAG
Publication type Dissertation, internally prepared
Publication year 2018
Abstract

For this thesis, the goal was to investigate:

1) the self-assembly of amine-terminated dendrimers into well-defined dendrimicelles

2) the use of the micelle embedded nanoparticles as ‘spy’ particles

3) the effect of a templating matrix on the self-organization of these dendrimicelles into mesoscale superstructures.

Throughout the thesis, it is shown that well-defined, 50 nm-sized dendrimicelles can be obtained from PAMAM dendrimer generations five through nine. By combining cryoTEM and light scattering experiments, the self-assembly behavior of the dendrimicelles is studied in unique detail. The dendrimicelle-embedded nanoparticles serve a dualistic purpose; not only do they provide additional contrast in the cryoTEM micrographs, they also allow for the direct determination of the micelle aggregation numbers by simply counting the number of nanoparticles.

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