Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 551889
Title A Natural Supramolecular Saponin Hydrogelator for Creation of Ultrastable and Thermostimulable Food-Grade Foams
Author(s) Ma, Lulu; Li, Qing; Du, Zhenya; Su, Enyi; Liu, Xiao; Wan, Zhili; Yang, Xiaoquan
Source Advanced Material Interfaces 6 (2019)14. - ISSN 2196-7350
DOI https://doi.org/10.1002/admi.201900417
Department(s) Physics and Physical Chemistry of Foods
Publication type Refereed Article in a scientific journal
Publication year 2019
Keyword(s) glycyrrhizic acid - responsive foams - saponin nanofibrils - supramolecular self-assembly - ultrastability
Abstract

A new class of food-grade foams that are ultrastable, thermostimulable, and processable can be created simply by using the naturally occurring saponin glycyrrhizic acid (GA) as the sole stabilizer. The creation of this “superfoam” is based on the spatially controllable self-assembly of supramolecular GA nanofibril hydrogelators at the air–water interface and in the continuous phase. The rapid adsorption of GA nanofibrils at the bubble surface, forming a multilayer interfacial network, combined with the formation of viscoelastic fibrillar hydrogel networks in the continuous phase, enables the foams having ultrastability over months or years without the water drainage induced phase separation, which have been evidenced using small angle X-ray scattering and microscopy techniques. Such ultrastable foams can be rapidly destabilized on demand by heating, which induces the melting of the fibrillar networks. These thermoresponsive foams can be reversibly switched between stable and unstable by simply changing the temperature, based on the reversible gel–sol phase transition of the supramolecular hydrogel inside the foam. This is the first finding of a natural edible surfactant system that foams very well and can be used solely to make advanced foams with the qualities of simplicity, ultrastability, stimulability, and processability, which make them viable for many sustainable applications.

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