Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 553484
Title Chain length-dependent luminescence in acceptor-doped conjugated polymers
Author(s) Scheer, Pieter van der; Laar, Ties van de; Sprakel, Joris
Source Scientific Reports 9 (2019)1. - ISSN 2045-2322 - 12 p.
DOI https://doi.org/10.1038/s41598-019-47537-2
Department(s) Physical Chemistry and Soft Matter
Publication type Refereed Article in a scientific journal
Publication year 2019
Abstract

Semiconducting polymers doped with a minority fraction of energy transfer acceptors feature a sensitive coupling between chain conformation and fluorescence emission, that can be harnessed for advanced solution-based molecular sensing and diagnostics. While it is known that chain length strongly affects chain conformation, and its response to external cues, the effects of chain length on the emission patterns in chromophore-doped conjugated polymers remains incompletely understood. In this paper, we explore chain-length dependent emission in two different acceptor-doped polyfluorenes. We show how the binomial distribution of acceptor incorporation, during the probabilistic polycondensation reaction, creates a strong chain-length dependency in the optical properties of this class of luminescent polymers. In addition, we also find that the intrachain exciton migration rate is chain-length dependent, giving rise to additional complexity. Both effects combined, make for the need to develop sensoric conjugated polymers of improved monodispersity and chemical homogeneity, to improve the accuracy of conjugated polymer based diagnostic approaches.

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