Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 560607
Title Direct analysis of aromatic hydrocarbons in purified mineral oils of foods and cosmetics applications using gas chromatography with vacuum ultraviolet detection
Author(s) Garcia Cicourel, A.R.; Janssen, Hans-Gerd
Source Journal of Chromatography. A, Including electrophoresis and other separation methods 1590 (2019). - ISSN 0021-9673 - p. 113 - 120.
DOI https://doi.org/10.1016/j.chroma.2019.01.015
Publication type Refereed Article in a scientific journal
Publication year 2019
Abstract Highly purified mineral oils are used in several pharmaceutical, foods and cosmetics applications. A fast and simple method was developed for the analysis of the total level of residual mineral oil aromatic hydrocarbons (MOAH) in these oils and in the intermediate oils that were sampled during the purification process. The method is based on gas chromatography with vacuum ultraviolet detection (GC-VUV) and relies on the spectral differences between the aliphatic and aromatic compounds in the sample. Because the detector provides a good selectivity for aromatics, direct quantification of the MOAH content is possible without the need for a laborious preseparation of the mineral oil. The method was successfully applied for the direct analysis of the MOAH levels of 18 different mineral oil samples. The aromatics contents obtained by GC-VUV were similar to those obtained using two conventional methods (NPLC-GC-FID and SPE-GC-FID), with no statistically significant difference. The detector response was linear over the concentration range tested (0.5–20 mg/mL) and the repeatability (RSD value) was less than 8%, which is better than the typical values for the conventional methods (up to 15% RSD). The minimum MOAH level that can be determined with this method is approximately 0.13%, making the GC-VUV method sufficiently sensitive for the analysis of all but the highest purity mineral oils.
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