Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 561329
Title Geochemical Multisurface Modeling of Reactive Zinc Speciation in Compost as Influenced by Extraction Conditions
Author(s) Klinkert, Susan; Comans, Rob N.J.
Source Environmental Science and Technology 54 (2020)4. - ISSN 0013-936X - p. 2467 - 2475.
DOI https://doi.org/10.1021/acs.est.9b04104
Department(s) Soil Chemistry and Chemical Soil Quality
WIMEK
Publication type Refereed Article in a scientific journal
Publication year 2020
Abstract Knowledge on organic matter (OM) concentration and composition is of major importance for predicting Zn speciation and bioavailability in soils, especially for low-Zn soils. However, comprehensive knowledge on the effect of soil-like organic amendments such as compost on metal speciation is limited. For the first time, multisurface modeling is applied on compost to study the effect of solid and dissolved OM composition on the speciation of reactive Zn as influenced by conditions applied in frequently used extractions to estimate Zn bioavailability. First, compost OM composition was determined by fractionation in operationally defined humic, fulvic, and hydrophilic acid pools under various extraction conditions, and subsequently, Zn speciation was modeled using the generic non-ideal competitive adsorption-Donnan (NICA-Donnan) model in addition to adsorption to hydrous ferric oxide (HFO) and clay. The results show a strong effect of extraction conditions on OM concentration and composition and related dissolved Zn speciation. Model predictions show that Zn in solution is mainly bound to dissolved humic acids. Analysis of deviations between measured and modeled Zn concentrations reveal specific limitations of the current generic model parameters, particularly with regard to Zn binding to OM at low concentrations and Ca-Zn competition, that is, typical conditions that occur in low-Zn soils.
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