Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

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Record number 561987
Title Asymmetric Monomer, Amorphous Polymer? Structure-Property Relationships in 2,4-FDCA and 2,4-PEF
Author(s) Nolasco, Mariela M.; Araujo, Catarina F.; Thiyagarajan, Shanmugam; Rudić, Svemir; Vaz, Pedro D.; Silvestre, Armando J.D.; Ribeiro-Claro, Paulo J.A.; Sousa, Andreia F.
Source Macromolecules 53 (2020)4. - ISSN 0024-9297 - p. 1380 - 1387.
DOI https://doi.org/10.1021/acs.macromol.9b02449
Department(s) BBP Sustainable Chemistry & Technology
Publication type Refereed Article in a scientific journal
Publication year 2020
Abstract

The biobased polyester poly(ethylene 2,4-furanoate) (2,4-PEF) is a potentially interesting yet insufficiently studied polymer whose resistance to crystallization fundamentally stems from the asymmetric nature of the 2,4-furandicarboxylic acid monomer. A combination of vibrational spectroscopy (infrared, Raman and inelastic neutron scattering) and ab initio calculations has been used to assess the conformational and regiochemistry preferences of 2,4-PEF. The latter polymerizes following a random distribution of monomer orientation, thereby rendering the formation of periodic interchain C-H···O contacts wholly unfeasible and ultimately favoring the formation of randomly coiled chains based on gauche-ethylene glycol segments. In the absence of C-H···O stabilization, the ordered crystalline arrangement is disfavored and polymer chains - adopting several quasi iso-energetic structures - prefer to solidify into an amorphous mess.

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