Staff Publications

Staff Publications

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    'Staff publications' is the digital repository of Wageningen University & Research

    'Staff publications' contains references to publications authored by Wageningen University staff from 1976 onward.

    Publications authored by the staff of the Research Institutes are available from 1995 onwards.

    Full text documents are added when available. The database is updated daily and currently holds about 240,000 items, of which 72,000 in open access.

    We have a manual that explains all the features 

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    A tribute to Jacques Buffle: founding father of dynamic metal speciation analysis
    Leeuwen, H.P. van; Wilkinson, K.J. ; Town, R.M. ; Sigg, L. - \ 2009
    Environmental Science and Technology 43 (2009)19. - ISSN 0013-936X - p. 7157 - 7158.
    Chemodynamics and bioavailability in natural waters
    Buffle, J. ; Wilkinson, K.J. ; Leeuwen, H.P. van - \ 2009
    Environmental Science and Technology 43 (2009)19. - ISSN 0013-936X - p. 7170 - 7174.
    dynamic speciation - nutrient uptake - metal flux - diffusion - transport - limitation - complexes - bacteria - biofilm - systems
    Environmental Colloids and Particles
    Buffle, J. ; Leeuwen, H.P. van; Wilkinson, K.J. ; Lead, J.R. - \ 2007
    Chichester : John Wiley and Sons (IUPAC Series on Analytical and Physical Chemistry of Environmental Systems 10) - ISBN 9780470024324 - 685 p.
    Humic substances are soft and permeable : evidence from their electrophoretic mobilities
    Duval, J.F.L. ; Wilkinson, K.J. ; Leeuwen, H.P. van; Buffle, J. - \ 2005
    Environmental Science and Technology 39 (2005)17. - ISSN 0013-936X - p. 6435 - 6445.
    fluorescence correlation spectroscopy - ion complexation equilibria - fulvic-acids - proton-binding - physicochemical description - polyelectrolyte properties - diffusion-coefficients - colloidal particles - organic-matter - ph
    Due to the complexity of the humic substances (HS), mathematical models have often been employed to understand their roles in the environment. Since no consensus exists with respect to the structure and conformation of the HS, models have alternatively given them properties corresponding to impermeable hard spheres or fully permeable polyelectrolytes. In this study, the hydrodynamic permeability of standard HS (Suwannee River fulvic, humic, and peat humic acids) are evaluated as a function of pH and ionic strength. A detailed theoretical model is used to determine the softness parameter (lambda0), which characterizes the degree of flow penetration into the HS on the basis of measured values of electrophoretic mobilities, diffusion coefficients, and electric charge densities. Their motion in an electric field is evaluated by a rigorous numerical evaluation of the governing electrokinetic equations for soft particles. The hydrodynamic impact of the polyelectrolyte chains is accounted for by a distribution of Stokes resistance centers and partial dissociation of the hydrodynamically immobile ionogenic groups distributed throughout the polyelectrolyte. The results demonstrate thatthe studied HS are small (radius ca. 1 nm), highly charged (500-650 C g(-1) when all sites are dissociated), and very permeable (typical flow penetration length of 25-50% of the radius, depending on pH). The HS also coagulate slightly when lowering the pH of the solution. Modeling of the HS as hard spheres with a charge and slip plane located at the surface is thus physically inappropriate, as are a number of analytical theories for soft particles that hold for low to moderate electrostatic potentials and large colloids. The shortcomings of these simpler approaches, when interpreting the electrophoretic mobilities of HS, are highlighted by comparison with rigorous theoretical predictions.
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