Nanomanufacturing of continuous composite nanofibers with confiment-induced morphologies
Kamperman, M.M.G. ; Korley, L.T.J. ; Yau, B. ; Johansen, K.M. ; Joo, Y.L. ; Wiesner, U. - \ 2010
Polymer Chemistry 1 (2010)7. - ISSN 1759-9954 - p. 1001 - 1004.
block-copolymer nanofibers - styrene triblock copolymer - high-temperature ceramics - lamellar morphology - electrospun fibers - diblock copolymers - diameter fibers - nanocomposites - mesostructures - microphase
Continuous core-shell nanofibers with poly(isoprene-block-dimethylaminoethyl methacrylate) (PI-b-PDMAEMA) block copolymer/polymer derived ceramic (PDC) precursor nanocomposites as cores enveloped in rigid polyacrylonitrile (PAN) shells were nanomanufactured using coaxial electrospinning. The cylindrical confinement imposed by the rigid shell led to ordered morphologies in the core not observed in bulk block copolymer nanocomposites.